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Structure Information
Structure

Compound Identification

SMILES

COC1=CC2=C(C=C1)[C@]1(C[C@H]3[C@H]4CO[C@@H]1C[C@H]4\C(C[N+]3=C(OCC(Cl)(Cl)Cl)O[Si](C)(C)C)=C/C)C(=O)N2

InChIKey

InChIKey=BLTAUYIGGLLSBR-YALLTKBQSA-O

Formula

C26H34Cl3N2O5Si

Mass

589.0

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Taxonomic Classification

Taxonomy Tree

Kingdom

Organic compounds

Superclass

Alkaloids and derivatives

Class

Gelsemium alkaloids

Subclass

Not available

Intermediate Tree Nodes

Not available

Direct Parent

Gelsemium alkaloids

Alternative Parents

Molecular Framework

Aromatic heteropolycyclic compounds

Substituents

Gelsemium skeleton - Indole or derivatives - Dihydroindole - Anisole - Phenol ether - Alkyl aryl ether - Oxepane - Oxane - Benzenoid - Piperidine - Trialkylheterosilane - Carboxamide group - Lactam - Secondary carboxylic acid amide - Carboximidic acid derivative - Organoheterosilane - Carboxylic acid derivative - Dialkyl ether - Ether - Oxacycle - Azacycle - Organic metalloid salt - Organoheterocyclic compound - Organohalogen compound - Carbonyl group - Hydrocarbon derivative - Organic oxide - Organic oxygen compound - Organic metalloid moeity - Organochloride - Organonitrogen compound - Organooxygen compound - Organic nitrogen compound - Alkyl chloride - Alkyl halide - Organosilicon compound - Organic cation - Aromatic heteropolycyclic compound

Description

This compound belongs to the class of organic compounds known as gelsemium alkaloids. These are alkaloids with a structure that is based on the tetracyclic gelsemium skeleton. These alkaloids contain an oxindole function and a cage-like, hydroaromatic residue which is believed to arise from an intermediate related to anhydrovobasinediol by formation of a 6,20 bond and rearrangement to an oxindole. The major alkaloids in this group are related to Gelsemine; however, a smaller group, characterized by Gelsedine, lack the 6,20 bond, and have also lost C-21.

External Descriptors

Not available

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