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Chemical category

Gelsemium alkaloids

Description

Alkaloids with a structure that is based on the tetracyclic gelsemium skeleton. These alkaloids contain an oxindole function and a cage-like, hydroaromatic residue which is believed to arise from an intermediate related to anhydrovobasinediol by formation of a 6,20 bond and rearrangement to an oxindole. The major alkaloids in this group are related to Gelsemine; however, a smaller group, characterized by Gelsedine, lack the 6,20 bond, and have also lost C-21.

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Below are a few examples of gelsemium alkaloids found in the ClassyFire database.

Example Entities

ID Structure Formula Mass
8532375 InChIKey=SLASDPLISJVCFA-LRWULUOQSA-N C26H34Cl3IN2O5Si 715.91 Show
8532395 InChIKey=REDULKRGAARDDI-YNBIHDICSA-O C26H34Cl3N2O5Si 589.0 Show
8556427 InChIKey=VPSRFQGSFLTXAE-SQMWYMQWSA-N C20H26N2O4 358.438 Show
8871429 InChIKey=XMZMYHAYGQPXSR-CORRHQHCSA-N C20H24N2O4 356.422 Show
8891964 InChIKey=YMCZQCYRJRRIDH-BGCLATTASA-N C19H24N2O3 328.412 Show
8894717 InChIKey=JBRTYQXRZWKPBC-YVPRTTNYSA-N C20H26N2O5 374.437 Show
9002076 InChIKey=FIXMISYVRHVDDT-XVYZKIFYSA-N C26H34Cl3IN2O5Si 715.91 Show
9002097 InChIKey=BLTAUYIGGLLSBR-YALLTKBQSA-O C26H34Cl3N2O5Si 589.0 Show
9383879 InChIKey=XMZMYHAYGQPXSR-DMVXCXLKSA-N C20H24N2O4 356.422 Show
9459621 InChIKey=ZREVWZNVVDYUMA-KXHDNATJSA-N C20H26N2O4 358.438 Show
9480313 InChIKey=LDBVYQSHIPCQPT-VDQLAVKBSA-N C19H24N2O3 328.412 Show
9502076 InChIKey=NMAOILPRGBGTEA-COBUNYNLSA-N C20H26N2O4 358.438 Show
9514728 InChIKey=JBRTYQXRZWKPBC-LXJIRDTFSA-N C20H26N2O5 374.437 Show
16413559 InChIKey=VSCNFOAMCNRXFZ-DFFYWDIOSA-N C21H26N2O5 386.448 Show
16392149 InChIKey=ADHSBPQCVJMTCZ-CCWRJCQXSA-N C20H24N2O3 340.423 Show
23393533 InChIKey=VXXWDIZFWYSBQA-AWPBHTPUSA-N C21H28N2O5 388.464 Show
23409681 InChIKey=SGOJVDWQVVFRIS-YVYVQPTCSA-N C23H25Cl3N2O5 515.81 Show
23411345 InChIKey=ZXRGGMATGWCUBP-WAOYUKJNSA-N C20H24N2O3 340.423 Show
23411348 InChIKey=LBJHXCKZOHFEGX-DOGZQJLVSA-N C27H28N2O5 460.53 Show
23799993 InChIKey=ILXSNNTYRNLDCX-NJFXSBFBSA-N C22H28N2O4 384.476 Show
23909434 InChIKey=NFYYATWFXNPTRM-GGWPIWIFSA-N C20H22N2O2 322.408 Show
33806599 InChIKey=AGNQRTMSASNUCN-MIICOSPZSA-N C19H20N2O3 324.38 Show
33806598 InChIKey=JLVYVHFZVDBPEL-QJICHLCESA-N C20H21N3O3 351.406 Show
45339470 InChIKey=OIUVQDDWCVENEM-BFDSESMSSA-N C35H43N5O4 597.76 Show
45794850 InChIKey=NFYYATWFXNPTRM-WKRGLROPSA-N C20H22N2O2 322.408 Show